Reaction of Nitromethane with Phenylacetylene in Superbasic Media

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Abstract

Nitromethane reacts with phenylacetylene in the KOH(t-BuOK)/DMSO superbase media to form E- and Z-isomers of 4-benzyl-3-styryl-4,5-dihydroisoxazole-2-oxide, 2-benzyl-3-hydroxypropanonitrile and 1-benzyl-2-nitrocyclopropane.

About the authors

N. A Lobanova

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

ORCID iD: 0000-0003-4594-1034
Irkutsk, Russia

I. V Tatarinova

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

ORCID iD: 0000-0001-6237-8533
Irkutsk, Russia

I. A Ushakov

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

ORCID iD: 0000-0003-0176-1699
Irkutsk, Russia

E. Yu Schmidt

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

ORCID iD: 0000-0002-0188-3015
Irkutsk, Russia

B. A Trofimov

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: boris_trofimov@irioch.irk.ru
ORCID iD: 0000-0002-0430-3215
Irkutsk, Russia

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