SOLUTION SYNTHESIS FROM VARIOUS PRECURSORS OF MAGNESIUM PHOSPHATE-BASED POWDER MATERIALS FOR STEREOLITHOGRAPHIC 3D PRINTING

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Abstract

Powders Mg3(PO4)2·22H2O, MgHPO4·3H2O, NaMg4(PO4)3·xH2O, NH4MgPO4·6H2O from different salts, magnesium oxide and phosphoric acid were synthesized by precipitation from solutions at 25°C. Depending on the precursors, products of different compositions were obtained at a specified pH = 9, they were characterized using X-ray diffraction, electron microscopy, and static light scattering. The selection of the sintering mode for the printed sample was carried out using TG and DTA to determine the temperature intervals at which the organic component of the printing suspension was removed. The fundamental possibility of obtaining porous ceramics by 3D printing from magnesium orthophosphate obtained by the solution method with an average size of agglomerates of 28.3 μm and Kelvin structure has been shown. This opens up prospects for the use of magnesium phosphate-based ceramics, in particular magnesium orthophosphate, in regenerative medicine.

About the authors

A. K Pupanova

Moscow State University

Email: aleksandra.pupanova@chemistry.msu.ru
Faculty of Chemistry Moscow, Russia

E. S Klimashina

Moscow State University; Moscow State University

Email: aleksandra.pupanova@chemistry.msu.ru

Faculty of Chemistry, Faculty of Materials Sciences

Moscow, Russia; Moscow, Russia

A. M Murashko

Moscow State University; Moscow State University

Email: aleksandra.pupanova@chemistry.msu.ru

Faculty of Chemistry, Faculty of Materials Sciences

Moscow, Russia; Moscow, Russia

Ya. Yu Filippov

Moscow State University; Institute of Mechanics, Moscow State University

Email: aleksandra.pupanova@chemistry.msu.ru

Faculty of Chemistry

Moscow, Russia; Moscow, Russia

P. V Evdokimov

Moscow State University; Moscow State University

Email: aleksandra.pupanova@chemistry.msu.ru

Faculty of Chemistry, Faculty of Materials Sciences

Moscow, Russia; Moscow, Russia

V. I Putlyaev

Moscow State University; Moscow State University

Author for correspondence.
Email: aleksandra.pupanova@chemistry.msu.ru

Faculty of Chemistry, Faculty of Materials Sciences

Moscow, Russia; Moscow, Russia

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