Selective limiting concentration of the electrolyte solutions with singly and doubly charged cations

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Abstract

The effect of the anion exchange layer of the copolymer N,N-diallyl-N,N-dimethylammonium chloride and methyl methacrylate on the electrochemical properties of a homogeneous perfluorosulfopolymer-based cation exchange membrane has been studied. Applying a modifying layer with a thickness of 5 microns to a membrane with a thickness of 215 microns leads to a decrease in electrical conductivity by no more than 35%, while the diffusion permeability decreases by more than 5 times and ceases to depend on concentration.

During membrane testing, similar levels of concentration were achieved in the process of the limiting electrodialysis concentration of sodium chloride solution. The effectiveness of a bilayer membrane for selective electrodialysis concentration was demonstrated. During the concentration of sodium and calcium chlorides mixture, the permselectivity coefficient P(Na+/Ca2+) ranged from 0.5 to 1.2 in the case of using the cation exchange membrane. Using a bilayer membrane led to a significant increase of the permselectivity coefficient, ranging from 1.5 to 2.7, depending on current density. This makes it possible to efficiently separate electrolytes with singly and doubly charged ions.

About the authors

N. O. Kovalchuk

Kuban State University; Platov South-Russian State Polytechnic University (NPI)

Author for correspondence.
Email: kovol13@yandex.ru
Russian Federation, Krasnodar; Novocherkassk

A. A. Minenko

Kuban State University

Email: kovol13@yandex.ru
Russian Federation, Krasnodar

N. A. Romanyuk

Kuban State University

Email: kovol13@yandex.ru
Russian Federation, Krasnodar

N. V. Smirnova

Platov South-Russian State Polytechnic University (NPI)

Email: kovol13@yandex.ru
Russian Federation, Novocherkassk

S. A. Loza

Kuban State University

Email: kovol13@yandex.ru
Russian Federation, Krasnodar

V. I. Zabolotsky

Kuban State University

Email: kovol13@yandex.ru
Russian Federation, Krasnodar

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