Synthesis and Study of Catalytic Properties of Rh-Containing Structured Catalyst for Diesel Fuel Conversion into Synthesis Gas

V. A. Shilov; Шилов В. А.; V. N. Rogozhnikov; Рогожников В. Н.; D. I. Potemkin; Потемкин Д. И.; P. V. Snytnikov; Снытников П. В.

doi:10.31857/S0453881123010070

Synthesis and Study of Catalytic Properties of Rh-Containing Structured Catalyst for Diesel Fuel Conversion into Synthesis Gas

Авторлар: Shilov V.A.¹^,2, Rogozhnikov V.N.¹, Potemkin D.I.¹^,2, Snytnikov P.V.¹
Мекемелер:
1. Boreskov Institute of Catalysis, Siberian Branch of Russian Academy of Science
2. Novosibisk State University
Шығарылым: Том 64, № 1 (2023)
Беттер: 109-118
Бөлім: ARTICLES
URL: https://vietnamjournal.ru/0453-8811/article/view/660296
DOI: https://doi.org/10.31857/S0453881123010070
EDN: https://elibrary.ru/KIURFI
ID: 660296

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат
Рұқсат жабық

Рұқсат берілді
Рұқсат жабық

Рұқсат ақылы немесе тек жазылушылар үшін

Аннотация

In this work, we improved the technique for depositing the active oxide Ce_0.75Zr_0.25O_{2 – δ} on a structured FeCrAl alloy substrate. The essence of the method is the coprecipitation of cerium and zirconium oxides on a FeCrAl grid from an aqueous solution of their nitrates Ce(NO₃)₃·6H₂O and ZrO₂(NO₃)₂·7–8H₂O during homogeneous hydrolysis with ammonia. It was shown by XRD analysis that in the sample obtained by co-precipitation, more cerium-zirconium oxide phase is formed, moreover, it is more dispersed than obtained by impregnation technique. This method contributes to the formation of a coating with a larger specific surface area. The developed catalyst has a high activity under the conditions of autothermal reforming of diesel fuel. In the course of life tests for 200 h, it was found that the carbonization of the catalyst at a rate of 8.6 mg_c $g_{cat}^{- 1}$ h^–1, as well as the accumulation of sulfur, did not affect the productivity of the catalyst with respect to synthesis gas, which was ~ 8 m³ $L_{cat}^{- 1}$ h^–1.

Негізгі сөздер

diesel fuel, structured catalyst, autothermal reforming, synthesis gas, fuel cell, hydrogen

Әдебиет тізімі

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