Electron paramagnetic resonance [Cu 3+ –Cu 2+ ](C 2v ) impurity dimers in BaF 2 :Cu ionic crystal

R. B. Zaripov; Зарипов Р. Б.; V. A. Ulanov; Уланов В. А.; R. I. Kalimullin; Калимуллин Р. И.

doi:10.31857/S0367676523703052

Electron paramagnetic resonance [Cu³⁺–Cu²⁺](C_2v) impurity dimers in BaF₂:Cu ionic crystal

Authors: Zaripov R.B.¹, Ulanov V.A.¹^,2, Kalimullin R.I.²
Affiliations:
1. Zavoisky Physical-Technical Institute, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”
2. Kazan State Power Engineering University
Issue: Vol 87, No 12 (2023)
Pages: 1767-1772
Section: Articles
URL: https://vietnamjournal.ru/0367-6765/article/view/654538
DOI: https://doi.org/10.31857/S0367676523703052
EDN: https://elibrary.ru/QKCQAV
ID: 654538

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Abstract
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Abstract

Impurity dimers [Cu³⁺–Cu²⁺] (С_2v) with an antiferromagnetic bond between copper ions have been synthesized in BaF₂ crystals. The study of the molecular structure of the synthesized dimers was carried out by the electron paramagnetic resonance at frequencies of 9.3 and 34.2 GHz in the temperature range from 5 to 150 K. It was shown that the ⁶³Cu³⁺ and ⁶³Cu²⁺ ions replaced the neighboring cations of the Ва²⁺ lattice, forming a dimer with a parallel bond axis of one of the 〈110〉 crystallographic axes. It has been found that the coupling between copper ions has an antiferromagnetic exchange interaction and that its repeated inverse state is a doublet, S = 1/2. There were determined parameters of Zeeman interaction, part of the parameters of the hyperfine and quadrupole interaction of ⁶³Cu³⁺ and ⁶³Cu²⁺ ions, as well as part of the parameters of the ligand hyperfine interaction with two equivalent F^– ions.

Keywords

EPR, barium fluoride, copper dimer [Cu³⁺–Cu²⁺], antiferromagnetic exchange, Jahn–Teller effect

References

Bersuker I.B. Electronic structure and properties of transition metal compounds. Introduction to the theory. N.Y.: Wiley, 1996.
Ulanov V.A., Krupski M., Hoffmann S.K., Zaripov M.M. // J. Phys. Cond. Matter. 2003. V. 15. No. 3. P. 1081.
Hoffmann S.K., Goslar J., Lijewski S., Ulanov V.A. // J. Chem. Phys. 2007. V. 127. Art. No.124705.
Уланов В.А., Зарипов М.М., Фазлижанов И.И. // ФТТ. 2005. Т. 47. № 9. С. 1596; Ulanov V.A., Zaripov M.M., Fazlizhanov I.I. // Phys. Solid. State. 2005. V. 47. No. 9. P. 1655.
Dorenbos P. Mechanism of ionic transport in rare earth doped alkaline earth fluorides. Druk: Krips Repro Meppel, 1988.
Mabbs F.E., Collison D. Electron paramagnetic resonance of d transition metal compounds. Elsevier Science Publishers, 1992.
Абрагам А., Блини Б. Электронный парамагнитный резонанс переходных ионов. Т. 1. М.: Мир, 1972.
Anderson P.W. // Phys. Rev. 1950. V. 79. P. 350.
Anderson P.W. // Phys. Rev. 1959. V. 115. P. 2.
Ашуров М.Х., Нуритдинов И., Бойбобоева С.Т. // Опт. и спектроск. 2023. Т. 131. № 3. С. 341; Ashurov M.K., Nuritdinov I., Boiboboeva S.T. // Opt. Spectrosc. 2023. V. 131. No. 3. P. 318.