Исследование возможности переноса насыщения в новом комплексе никеля(II) с 2,6-бис(пиразол-3-ил)пиридином

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Resumo

By reacting the N,N'-disubstituted 2,6-bis(pyrazol-3-yl)pyridine ligand (L) with a divalent nickel salt, a new nickel(II) complex [Ni(L)(H2O)(THF)Cl]BPh4 was obtained (I), which was isolated in individual form and characterized by elemental analysis, mass spectrometry, NMR spectroscopy and X-ray diffraction (CCDC No. 2221412). According to NMR spectroscopy data in combination with the results of quantum chemical calculations, complex I in solution does not exhibit a saturation transfer effect.

Sobre autores

D. Aleshin

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia

Email: unelya@ineos.ac.ru
Россия, Москва

I. Nikovskii

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia

Email: unelya@ineos.ac.ru
Россия, Москва

E. Khakina

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia; Russia National Research University Higher School of Economics Moscow, Russia

Email: unelya@ineos.ac.ru
Россия, Москва; Россия, Москва

A. Danshina

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia; Moscow Institute of Physics and Technology (National Research University), Dolgoprudnyi, Moscow oblast, Russia

Email: unelya@ineos.ac.ru
Россия, Москва; Россия, Долгопрудный

Yu. Nelyubina

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia; Bauman State Technical University, Moscow, Russia

Autor responsável pela correspondência
Email: unelya@ineos.ac.ru
Россия, Москва; Россия, Москва

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Declaração de direitos autorais © Д.Ю. Алешин, И.А. Никовский, Е.А. Хакина, А.А. Даньшина, Ю.В. Нелюбина, 2023