First Example of Coordination Polymer Based on Tetrahedral Cluster Cyanocomplex of Rhenium and Barium

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Abstract

In this work, the interaction of the anionic tetrahedral cluster complex of rhenium [Re4(AsO)4(CN)12]8– with Ba2+ was investigated. The reaction under hydrothermal conditions results in the formation of a framework coordination polymer [{Ba4(H2O)9}Re4(AsO)4(CN)12]·15H2O (I). The coordination polymer is formed from cluster anions [Re4(AsO)4(CN)12]8– and cationic fragments [{Ba4(H2O)9}8+, linked by CN– bridges. The resulting compound was characterized by single crystal X-ray diffraction (CCDC no. 2441985), PXRD, IR and elemental analysis.

About the authors

A. V Ermolaev

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: ermolaev@niic.nsc.ru
ORCID iD: 0000-0002-6230-2528
PhD in Chemistry, Researcher Novosibirsk, Russian Federation

Yu. V Mironov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: yuri@niic.nsc.ru
ORCID iD: 0000-0002-8559-3313
Dr. Sci. in Chemistry, Chief Researcher Novosibirsk, Russian Federation

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