Synthesis and Structure of Manganese Complexes with N,N’-bis[(2,4,6-trimethylphenyl)imino]acenaphthene

Cover Page

Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription or Fee Access

Abstract

Methods for the synthesis of new manganese(II) complexes with N,N’-bis[(2,4,6-trimethylphenyl) imino (acenaphthene (Tmp-bian), [Mn(Tmp-bian)Br2] (I), [Mn(Tmp-bian)(EtOH)Br2] (Ia), [Mn(Tmpbian) Cl2] (II), [Mn(Tmp-bian)2 (ClO4) 2] (III), and [Mn(Tmp-bian)2(OTs)2] (IV) were developed. The obtained compounds were characterized by elemental analysis and IR spectroscopy. The molecular structures of I, Iа, and III were determined by X-ray diffraction (CCDC no. 233510–233512). The electronic structures of I and III were established by quantum chemical calculations using density functional theory (DFT).

Full Text

Restricted Access

About the authors

Yu. A. Laricheva

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Email: nikolaj.romashev75@gmail.com
Russian Federation, Novosibirsk

Ch. Guan

Novosibirsk National Research State University

Email: nikolaj.romashev75@gmail.com
Russian Federation, Novosibirsk

N. V. Kuratieva

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Email: nikolaj.romashev75@gmail.com
Russian Federation, Novosibirsk

N. F. Romashev

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Author for correspondence.
Email: nikolaj.romashev75@gmail.com
Russian Federation, Novosibirsk

A. L. Gushchin

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Email: nikolaj.romashev75@gmail.com
Russian Federation, Novosibirsk

References

  1. Kallmeier F., Kempe R. // Angew. Chem. Int. Ed. 2018. V. 57. № 1. P. 46.
  2. Najafpour M. M., Allakhverdiev S. I. // Int. J. Hydrogen Energy. 2012. V. 37. № 10. P. 8753.
  3. Mallick Ganguly O., Moulik S. // Dalton Trans. 2023. V. 52. № 31. P. 10639.
  4. Vinogradova K. A., Shekhovtsov N. A., Berezin A. S. et al. // Inorg. Chem. Commun. 2019. V. 100. P. 11.
  5. Berezin A.S., Vinogradova K.A., Nadolinny V.A. et al. // Dalton Trans. 2018. V. 47. № 5. P. 1657.
  6. Artem’Ev A.V., Davydova M.P., Berezin A.S. et al. // ACS Appl. Mater. Interfaces. 2022. V. 14. № 27. P. 31000.
  7. Davydova M. ., Bauer I.A., Brel V.K. et al. // Eur. J. Inorg. Chem. 2020. V. 2020. № 8. P. 695–703.
  8. Artem’ev A.V., Davydova M.P., Rakhmanova M.I. et al. // Inorg. Chem. Front. 2021. V. 8. № 15. P. 3767.
  9. Artem’ev A.V., Kashevskii A.V., Bogomyakov A.S. et al. // Dalton Trans. 2017. V. 46. № 18. P. 5965.
  10. Hu J. Q., Song E. H., Ye S. et al // J. Mater. Chem. C. 2017. V. 5. № 13. P. 3343.
  11. Zou S., Liu Y., Li J. et al. // J. Am. Chem. Soc. 2017. V. 139. № 33. P. 11443.
  12. Davydova M., Meng L., Rakhmanova M.I. et al. // Adv. Mater. 2023. V. 35. № 35. P. 2303611.
  13. Qin Y., She P., Huang X., Huang W. et al. // Coord. Chem. Rev. 2020. V. 416. P. 213331
  14. van Asselt R., Gielens E.E.C.G., Rülke R.E. et al. // J. Am. Chem. Soc. 1994. V. 116. № 3. P. 977.
  15. Fomenko I.S., Romashev N.F., Gushchin. A.L. // Coord. Chem. Rev. 2024. V. 514. P. 215845.
  16. Fedushkin I.L., Skatova A.A., Chudakova V.A. et al. // Angew. Chem. Int. Ed. 2003. V. 42. № 28. P. 3294.
  17. Bernauer J., Pölker J., Jacobi von Wangelin A. // ChemCatChem. 2022. V. 14. № 1. Art. e202101182.
  18. Fomenko I.S., Koshcheeva O.S., Kuznetsova N.I. et al. // Catalysts. 2023. V. 13. № 5. P. 849.
  19. Fomenko I. S., Gongola M. I., Shul’pina L. S. et al. // Catalysts. 2022. V. 12. № 10. P. 1168.
  20. Komlyagina V.I., Romashev N.F., Kokovkin V. et al. // Molecules. 2022. V. 27. № 20. P. 6961.
  21. Komlyagina V.I., Romashev N.F., Besprozvannykh V.K. et al. // Inorg. Chem. 2023. V. 62. № 29. P. 11541.
  22. Romashev N.F., Abramov P.A., Bakaev I. et al. // Inorg. Chem. 2022. V. 61. № 4. P. 2105.
  23. Hasan K., Zysman-Colman E. // Inorg. Chem. 2012. V. 51. № 22. P. 12560.
  24. Geary E.A.M., Yellowlees L.J., Jack L.A. et al. // Inorg. Chem. 2005. V. 44. № 2. P. 242.
  25. Bakaev I.V., Romashev N.F., Komlyagina V.I. et al. // New J. Chem. 2023. V. 47. № 40. P. 18825.
  26. Schmiege B.M., Carney M.J., Small B.L. et al. // Dalton Trans. 2007. № 24. P. 2547.
  27. Zhou M., Li X., Bu D.et al. // Polyhedron. 2018. V. 148. P. 88.
  28. Carrington S.J., Chakraborty I., Mascharak P.K. // Dalton Trans. 2015. V. 44. № 31. P. 13828.
  29. Fedushkin I.L., Sokolov V.G., Makarov V.M. et al. // Russ. Chem. Bull. 2016. V. 65. № 6. P. 1495.
  30. Bermejo M.R., Perez M.C., Fondo M. et al. // Synth. React. Inorg. Met. Chem. 1997. V. 27. № 7. P. 1009.
  31. Girolami G.S. // Inorg. Synth. 2002. V. 33. P. 91.
  32. El-Ayaan U., Murata F., El-Derby S. et al. // J. Mol. Struct. 2004. V. 692. № 1–3. P. 209.
  33. te Velde G., Bickelhaup, F.M., Baerends E.J. et al. // J. Comput. Chem. 2001. V. 22. № 9. P. 931.
  34. Van Lenthe E., Baerends E.J. // J. Comput. Chem. 2003. V. 24. № 9. P. 1142.
  35. Van Lenthe E., Snijders J.G., Baerends E.J. // J. Chem. Phys. 1996. V. 105. № 15. P. 6505.
  36. APEX2 (version 2.0), SAINT (version 8.18c), and SADABS (version 2.11), Bruker Advanced X-ray Solutions. Madison (WI, USA): Bruker AXS Inc., 2000–2012.
  37. Bruker Apex3 software suite: Apex3, SADABS-2016/2 and SAINT, version 2019.1-0; Bruker AXS Inc.: Madison, WI, 2017.
  38. Sheldrick G.M. SADABS. Program for Scaling and Correction of Area Detector Data. Göttingen (Germany): Unive. of Göttingen, 1996.
  39. Sheldrick G.M. // Acta Crystallogr. C. 2015. V. 71. № 1. P. 3.
  40. Singh G., Kapoor I.P.S., Kumar D. et al. // Inorg. Chim. Acta. 2009. V. 362. № 11. P. 4091.

Supplementary files

Supplementary Files
Action
1. JATS XML
Download
2. Scheme 1. Synthesis of Mn/BIAN complexes

Download (380KB)
Indexing metadata
3. Scheme 2. Synthesis of Mn/BIAN organometallic complexes

Download (100KB)
Indexing metadata
4. Scheme 3

Download (50KB)
Indexing metadata
5. Scheme 4. Synthesis of manganese complexes I-IV

Download (274KB)
Indexing metadata
6. Fig. 1. Molecular structure of complexes I and Ia according to PCA data. The insets show the selected angles of the Mn-Br(2)-N(2) (left) and Mn-Br(2)-N(2)-O (right) coordination unit. Hydrogen atoms are omitted for clarity

Download (176KB)
Indexing metadata
7. Fig. 2. Molecular structure of complex III according to PCA data (a); selected angles of the Mn-N(2)-O(2) coordination unit (b). Hydrogen atoms are not shown

Download (169KB)
Indexing metadata
8. Fig. 3. General view and energy levels of the boundary orbitals for the ground state of complex I. VZMO, VZMO-1, VZMO-2, VZMO-3, NSMO, NSMO+1 are shown

Download (214KB)
Indexing metadata
9. Fig. 4. General view and energy levels of the boundary orbitals for the ground state of complex III. VZMO, VZMO-1, VZMO-2, VZMO-3, NSMO, NSMO+1 are shown

Download (265KB)
Indexing metadata

Copyright (c) 2024 Российская академия наук