电邮这篇文章 Heteroleptic Cobalt Complexes with Abnormally Coordinated N-Heterocyclic Carbene
- 作者: Petrov P.A.1, Nikolaevskii S.A.2, Yambulatov D.S.2, Sukhikh T.S.1, Starikova A.A.3, Kiskin M.A.2, Sokolov M.N.1, Eremenko I.L.2
-
隶属关系:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
- Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russia
- 期: 卷 49, 编号 7 (2023)
- 页面: 398-405
- 栏目: Articles
- URL: https://vietnamjournal.ru/0132-344X/article/view/667494
- DOI: https://doi.org/10.31857/S0132344X22600527
- EDN: https://elibrary.ru/YJHFWF
- ID: 667494
如何引用文章
开放存取
##reader.subscriptionAccessGranted##
订阅或者付费存取
详细
The reaction of cobalt pivalate [Co(Piv)2]n and in situ generated N‑heterocyclic carbene IPrPh (1,3-bis(2,6-diisopropylphenyl)-2-phenylimidazol-4-ylidene) affords heteroligand complexes [Co2(Piv)4-(IPrPh)2] (I), [Co2(Piv)2.8(OtBu)1.2(IPrPh)2] (II), and [Co3(μ3-O)(Piv)4(IPrPh)2] (III). The structures of complexes II·C6H14 and III are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 2216724 and 2216725, respectively). Exchange spin-spin interactions between the magnetic Со2+ ions in the synthesized compounds are estimated by quantum chemical calculations.
作者简介
P. Petrov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
Email: panah@niic.nsc.ru
Россия, Новосибирск
S. Nikolaevskii
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
Email: sanikol@igic.ras.ru
Россия, Москва
D. Yambulatov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
Email: sanikol@igic.ras.ru
Россия, Москва
T. Sukhikh
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
Email: sanikol@igic.ras.ru
Россия, Новосибирск
A. Starikova
Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russia
Email: sanikol@igic.ras.ru
Россия, Ростов-на-Дону
M. Kiskin
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
Email: sanikol@igic.ras.ru
Россия, Москва
M. Sokolov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
Email: sanikol@igic.ras.ru
Россия, Новосибирск
I. Eremenko
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
编辑信件的主要联系方式.
Email: sanikol@igic.ras.ru
Россия, Москва
参考
- N-Heterocyclic Carbenes: From Laboratory Curiosities to Efficient Synthetic Tools / Ed. Diez-Gonzalez S. Croydon (UK): The Royal Society of Chemistry, 2016.
- Hopkinson M.N., Richter C., Schedler M., Glorius F. // Nature. 2014. V. 510. P. 485.
- Wang D., Leng X., Ye S., Deng L. // J. Am. Chem. Soc. 2019. V. 141. P. 7731.
- Sinha N., Pfund B., Wegeberg C. et al. // J. Am. Chem. Soc. 2022. V. 144. P. 9859.
- Smith J.M., Long J.R. // Inorg. Chem. 2010. V. 49. P. 11223.
- Zolnhofer E.M., Käß M., Khusniyarov M.M. et al. // J. Am. Chem. Soc. 2014. V. 136. P. 15072.
- Massard A., Braunstein P., Danopoulos A.A. et al. // Organometallics. 2015. V. 34. P. 2429.
- Bellan E.V., Poddel’sky A.I., Protasenko N.A. et al. // ChemistrySelect. 2016. V. 1. P. 2988.
- Hu X., Castro-Rodriguez I., Meyer K. // J. Am. Chem. Soc. 2004. V. 126. P. 13464.
- Gao Y., Li G., Deng L. // J. Am. Chem. Soc. 2018. V. 140. P. 2239.
- Tokmic K., Markus C.R., Zhu L., Fout A.R. // J. Am. Chem. Soc. 2016. V. 138. P. 11907.
- Wang D., Lai Y., Wang P et al. // J. Am. Chem. Soc. 2021. V. 143. P. 12847.
- Mo Z., Xiao J., Gao Y., Deng L. // J. Am. Chem. Soc. 2014. V. 136. P. 17414.
- Liu Y., Deng L. // J. Am. Chem. Soc. 2017. V. 139. P. 1798.
- Yu R.P., Darmon J.M., Milsmann C. // J. Am. Chem. Soc. 2013. V. 135. P. 13168.
- Harris C.F., Bayless M.B., van Leest N.P. // Inorg. Chem. 2017. V. 56. P. 12421.
- Deng L., Bill E., Wieghardt K., Holm R.H. // J. Am. Chem. Soc. 2009. V. 131. P. 11213.
- Tokmic K., Greer R.B., Zhu L., Fout A.R. // J. Am. Chem. Soc. 2018. V. 140. P. 14844.
- Yao X.-N., Du J.-Z., Zhang Y.-Q. et al. // J. Am. Chem. Soc. 2017. V. 139. P. 37.
- Ghadwal R.S., Reichmann S.O., Herbst-Irmer R. // Chem. Eur. J. 2015. V. 21. P. 4247.
- Rottschäfer D., Glodde T., Neumann B. et al. // Chem. Commun. 2020. V. 56. P. 2027.
- Nikolaevskii S.A., Petrov P.A., Sukhikh T.S. et al. // In-org. Chim. Acta. 2020. V. 508. P. 119643.
- Yambulatov D.S., Petrov P.A., Nelyubina Y.V. et al. // Mendeleev Commun. 2020. V. 30. P. 293.
- Yambulatov D.S., Nikolaevskii S.A., Shmelev M.A. et al. // Mendeleev Commun. 2021. V. 31. P. 624.
- Gordon A.J., Ford R.A. The Chemist’s Companion: A Handbook of Practical Data, Techniques, and References. N.Y.: Wiley, 1972.
- Petrov P.A., Smolentsev A.I., Bogomyakov A.S., Konchenko S.N. // Polyhedron. 2017. V. 129. P. 60.
- Apex3 software suite: Apex3, SADABS-2016/2 and SAINT. Version 2018.7-2. Madiso (WI, USA): Bruker AXS Inc., 2017.
- Sheldrick G.M. // Acta Crystallogr. A. 2015. V. 71. P. 3.
- Sheldrick G.M. // Acta Crystallogr. C. 2015. V. 71. P. 3.
- Dolomanov O.V., Bourhis L.J., Gildea R.J. et al. // J. A-ppl. Crystallogr. 2009. V. 42. P. 339.
- Frisch M.J., Trucks G.W., Schlegel H.B. et al. Gaussian 16. Revision C. 01. Wallingford: Gaussian, 2016.
- Becke A.D. // J. Chem. Phys. 1992. V. 96. P. 2155.
- Grimme S., Ehrlich S., Goerigk L. // J. Comput. Chem. 2011. V. 32. P. 1456.
- Chegerev M.G., Piskunov A.V., Tsys K.V. et al. // Eur. J. Inorg. Chem. 2019. V. 2019. P. 875.
- Tsys K.V., Chegerev M.G., Fukin G.K. et al. // Mendeleev Commun. 2020. V. 30. P. 205.
- Noodleman L. // J. Chem. Phys. 1981. V. 74. P. 5737.
- Shoji M., Koizumi K., Kitagawa Y. et al. // Chem. Phys. Lett. 2006. V. 432. P. 343.
- Chemcraft. Version 1.8. 2014. http://www.chemcraftprog.com
- Ghadwal R.S., Lamm J.-H., Rottschäfer D. et al. // Dalton Trans. 2017. V. 46. P. 7664.
补充文件
