Preorganized Amide Ligands Based on Resorcincalix[4]arene Platform

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Abstract

By exhaustive functionalization of rccc-tetra-C-phenethylresorcincalix[4]arene, new modified derivatives containing 8 terminal amide fragments and differing in components and size of spacers connecting the macrocyclic core with them, as well as the nature of amide groups, were synthesized. Using UV spectroscopy, acceptor properties of amide resorcinarenes towards metal cations under heterogeneous and homogeneous conditions were studied. The effect of macrocyclic core preorganization of ligand on its ability to form complex with metal cations was demonstrated.

About the authors

V. V. Glushko

Institute of Biology and Chemistry, Moscow Pedagogical State University

Email: vv.glushko@mpgu.su
Moscow, 129164 Russia

O. S. Serkova

Institute of Biology and Chemistry, Moscow Pedagogical State University; Pirogov Russian National Research Medical University

Email: vv.glushko@mpgu.su
Moscow, 129164 Russia; Moscow, 117997 Russia

A. V. Kamkina

Institute of Biology and Chemistry, Moscow Pedagogical State University

Email: vv.glushko@mpgu.su
Moscow, 129164 Russia

I. I. Levina

Emanuel Institute of Biochemical Physics of the Russian Academy of Sciences

Email: vv.glushko@mpgu.su
Moscow, 119334 Russia

I. Yu. Toropygin

Institute of Biomedical Chemistry

Author for correspondence.
Email: vv.glushko@mpgu.su
Moscow, 119121 Russia

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