Hydrothermal Synthesis and Photocatalytic Properties of Cobalt-Doped Tungsten Oxide

G. S. Zakharova; Захарова Г. С.; N. V. Podval’naya; Подвальная Н. В.; T. I. Gorbunova; Горбунова Т. И.; M. G. Pervova; Первова М. Г.

doi:10.31857/S0044457X22602127

Hydrothermal Synthesis and Photocatalytic Properties of Cobalt-Doped Tungsten Oxide

Autores: Zakharova G.S.¹, Podval’naya N.V.¹, Gorbunova T.I.², Pervova M.G.²
Afiliações:
1. Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences
2. Postovsky Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences
Edição: Volume 68, Nº 4 (2023)
Páginas: 435-443
Seção: СИНТЕЗ И СВОЙСТВА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
URL: https://vietnamjournal.ru/0044-457X/article/view/665265
DOI: https://doi.org/10.31857/S0044457X22602127
EDN: https://elibrary.ru/FMYUIV
ID: 665265

Citar

Texto integral

Acesso aberto
Acesso é fechado

Acesso está concedido
Acesso é fechado

Acesso é pago ou somente para assinantes

Resumo

Hexagonal tungsten trioxide–base interstitial solid solutions of general formula CoxWO3, where 0.01 ≤ x ≤ 0.09, were prepared hydrothermally. The dopant homogeneity extent was found to depend on рН in the working solution. Interstitial solid solutions with the highest Co2+ concentrations were formed at рН of 2.3. The CoxWO3 samples with a fiber-like morphology with a fiber diameter of ca. 40 nm, which were prepared at рН of 2.3, had the highest specific surface area, equal to 38.6 m2/g. The key parameter for the stability of the CoxWO3 crystal structure appeared to be ammonium ions residing in the hexagonal channels of the crystal structure. When tested as photocatalysts of 1,2,4-trichlorobenzene oxidation under the UV light, the prepared samples showed high chloroarene conversions and low selectivities to yield a wide range of organic compounds, including chlorine-free ones.

Palavras-chave

tungsten oxide, doping, cobalt, hydrothermal synthesis, photocatalysis

Bibliografia

Zheng H., Ou J.Z., Strano M.S. et al. // Adv. Funct. Mater. 2011. V. 21. № 12. P. 2175. https://doi.org/10.1002/adfm.201002477
Huang Z.-F., Song J., Pan L. et al. // Adv. Mater. 2015. V. 27. № 36. P. 5309. https://doi.org/10.1002/adma.201501217
Бушкова Т.М., Егорова А.А., Хорошилов А.В. и др. // Журн. неорган. химии. 2021. Т. 66. № 4. С. 470.
Bently J., Desai S., Bastakoti B.P. // Chem. Eur. J. 2021. V. 27. № 36. P. 9241. https://doi.org/10.1002/chem.202100649
Lei G., Lou C., Liu X. et al. // Sens. Actuators B. Chem. 2021. V. 341. № 15. P. 129996. https://doi.org/10.1016/j.snb.2021.129996
Purushothaman K.K., Muralidharan G., Vijayakumar S. // Mater. Lett. 2021. V. 296. 129881. https://doi.org/10.1016/j.matlet.2021.129881
Zheng F., Xi C., Xu J. et al. // J. Alloys Compd. 2019. V. 772. P. 933. https://doi.org/10.1016/j.jallcom.2018.09.085
Филиппова А.Д., Румянцев А.А., Баранчиков А.Е. и др. // Журн. неорган. химии. 2022. Т. 67. № 6. С. 706.
Murillo-Sierra J.C., Hernández-Ramírez A., Hinojosa-Reyes L. et al. // Chem. Eng. J. Adv. 2021. V. 5. 100070. https://doi.org/10.1016/j.ceja.2020.100070
Dong P., Hou G., Xi X. et al. // Environ. Sci.: Nano. 2017. V. 4. № 3. P. 539. https://doi.org/10.1039/c6en00478d
Dutta V., Sharma S., Raizada P. et al. // J. Environ. Chem. Eng. 2021. V. 9. № 1. 105018. https://doi.org/10.1016/j.jece.2020.105018
Razali N.A.M., Salleh W.N.W., Aziz F. et al. // J. Clean. Prod. 2021. V. 309. 127438. https://doi.org/10.1016/j.jclepro.2021.127438
Khaki M.R.D., Shafeeyan M.S., Raman A.A.A. et al. // J. Environ. Manag. 2017. V. 198. № 2. P. 78. https://doi.org/10.1016/j.jenvman.2017.04.099
Jacob K.A., Peter P.M., Jose P.E. et al. // Mater. Today: Proc. 2022. V. 49. № 2. 1408. https://doi.org/10.1016/j.matpr.2021.07.104
Song H., Li Y., Lou Z. et al. // Appl. Catal. B: Environ. 2015. V. 166–167. № 5. P. 112. https://doi.org/10.1016/j.apcatb.2014.11.020
Solarska R., Alexander B.D., Braun A. et al. // Electrochim. Acta. 2010. V. 55. № 26. P. 7780. https://doi.org/10.1016/j.electacta.2009.12.016
Shannow R.D. // Acta Crystallogr. A. 1976. V. 32. № 5. P. 751. https://doi.org/10.1107/S0567739476001551
Mehmood F., Iqbal J., Jan T. et al. // Vib. Spectr. 2017. V. 93. P. 78. https://doi.org/10.1016/j.vibspec.2017.09.005
Sun S., Chang X., Li Z. // Mater. Charact. 2012. V. 73. P. 130. https://doi.org/10.1016/j.matchar.2012.08.005
Sivakarthik P., Thangaraj V., Parthibavarman M. // J. Mater. Sc.: Mater. Electron. 2017. V. 28. № 8. P. 5990. https://doi.org/10.1007/s10854-016-6274-7
Liu Z., Liu B., Xie W. et al. // Sens. Actuators B Chem. 2016. V. 235. P. 614. https://doi.org/10.1016/j.snb.2016.05.140
Shen K., Sheng K., Wang Z. et al. // Appl. Surf. Sci. 2020. V. 501. P. 144003. https://doi.org/10.1016/j.apsusc.2019.144003
Lim J.-C., Jin C., Choi M.S. et al. // Ceram. Int. 2021. V. 47. № 15. P. 20956. https://doi.org/10.1016/j.ceramint.2021.04.095
Hariharan V., Aroulmoji V., Prabakaran K. et al. // J. Alloys Compd. 2016. V. 689. P. 41. https://doi.org/10.1016/j.jallcom.2016.07.136
Kumar R.D., Karuppuchamy S. // J. Alloys Compd. 2016. V. 674. P. 384. https://doi.org/10.1016/j.jallcom.2016.03.074
Dalenjan F.A., Bagheri-Mohagheghi M.M., Shirpay A. // J. Solid State Electrochem. 2022. V. 22. № 2. P. 401. https://doi.org/10.1007/s10008-021-05076-9
Jia Q., Ji H., Gao P. et al. // J. Mater. Sci.: Mater. Electron. 2015. V. 26. № 8. P. 5792. https://doi.org/10.1007/s10854-015-3138-5
Sing K.S.W., Everett D.H., Haul R.A.W. et al. // Pure Appl. Chem. 1985. V. 57. № 4. P. 603. https://doi.org/10.1351/pac198557040603
Moura J.V.B., Silveira J.V., da Silva Filho J.G. et al. // Vib. Spectrosc. 2018. V. 98. P. 98. https://doi.org/10.1016/j.vibspec.2018.07.008
Szilágyi I.M., Wang L., Gouma P.-I. et al. // Mater. Res. Bull. 2009. V. 44. № 3. P. 505. https://doi.org/10.1016/j.materresbull.2008.08.003
Szilágyi I.M., Madarász J., Pokol G. et al. // Chem. Mater. 2008. V. 20. № 12. P. 4116. https://doi.org/10.1021/cm800668x
Mohamed M.M., Salama T.M., Hegazy M.A. et al. // Int. J. Hydrogen Energy. 2019. V. 44. № 10. P. 4724. https://doi.org/10.1016/j.ijhydene.2018.12.218
ThOny A., Rossi M.J. // J. Photochem. Photobiol. A. 1997. V. 104. № 1–3. P. 25.
van Wijk D., Cohet E., Gard A. et al. // Chemosphere. 2006. V. 62. № 8. P. 1294. https://doi.org/10.1016/j.chemosphere.2005.07.010
Zolezzi M., Cattaneo C., Tarazona J.V. // Environ. Sci. Technol. 2005. V. 39. № 9. P. 2920. https://doi.org/10.1021/es049214x
Horikoshi S., Minami D., Ito S. et al. // J. Photochem. Photobiol. A. 2011. V. 217. № 1. P. 141. https://doi.org/10.1016/j.jphotochem.2010.10.001
Dong W.H., Zhang P., Lin X.Y. et al. // Sci. Total Environ. 2015. V. 505. P. 216. https://doi.org/10.1016/j.scitotenv.2014.10.002