Subsolidus Phase Equilibria in the Ni–Mn–Ga–Sb and Ni–Mn–In–Sb Systems

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Abstract

The analysis of phase equilibria in the Ni–Mn–Ga–Sb and Ni–Mn–In–Sb systems in the absence of melt is carried out. The method of topological modeling based on the concentration diagrams of the ternary systems Ni–Mn–Sb, Ni–Mn–Ga, Ni–Mn–In, Ni–Ga–Sb, Ni–In–Sb, Mn–Ga–Sb, Mn–In–Sb and fragmentary experimental data on phase equilibria involving the Heusler intermetallics Ni2Mn1+x(Ga,Sb)1–x and Ni2Mn1+x(In,Sb)1–x are constructed isobaric-isothermal subsolidus concentration diagrams of the quaternary systems Ni–Mn–Ga–Sb and Ni–Mn–In–Sb. Their main differences are shown.

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About the authors

M. N. Smirnova

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Author for correspondence.
Email: smirnovamn@igic.ras.ru
Russian Federation, 31, Leninsky Ave., Moscow, 119991

G. A. Buzanov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: smirnovamn@igic.ras.ru
Russian Federation, 31, Leninsky Ave., Moscow, 119991

G. D. Nipan

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: smirnovamn@igic.ras.ru
Russian Federation, 31, Leninsky Ave., Moscow, 119991

O. N. Pashkova

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: smirnovamn@igic.ras.ru
Russian Federation, 31, Leninsky Ave., Moscow, 119991

G. E. Nikiforova

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: smirnovamn@igic.ras.ru
Russian Federation, 31, Leninsky Ave., Moscow, 119991

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2. Fig. 1. Diagrams of ternary systems in Ni-Mn-Ga-Sb (a) and Ni-Mn-In-Sb (b) tetrahedra.

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3. Fig. 2. Isobaric-isothermal diagrams of Ni-Mn-Ga-Sb (a) and Ni-Mn-In-Sb (b) systems.

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