Phase Equilibria in the Li–V–O System (Analytical Review)

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Abstract

Using the method of topological modeling and basing on fragmentary experimental data on phase equilibria and transformations, P–T–x phase diagrams of binary systems Li–V, Li–O, V–O, as well as a complete isothermal concentration diagram of the Li–V–O system, which take into account the formation of limited solid solutions and the presence of saturated vapor, were constructed for the first time.

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About the authors

G. D. Nipan

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Author for correspondence.
Email: nipan@igic.ras.ru
Russian Federation, Moscow, 119071

G. A. Buzanov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: nipan@igic.ras.ru
Russian Federation, Moscow, 119071

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Supplementary files

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2. Fig. 1. P-T- (a) and T-x-projections (b) of the P-T-x-phase diagram of Li-V.

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3. Fig. 2. Isobaric T-x-sections of the P-T-x-phase diagram of Li-V: interval POLi < P < PM (a) and P = 101 kPa (b).

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4. Fig. 3. P-T- (a) and T-x-projections (b) of the P-T-x-phase diagram of Li-O.

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5. Fig. 4. Isobaric T-x-sections of the P-T-x-phase diagram of Li-O: intervals POLi < P < PN1 (a), PN1 < P < PN2 (b), PN2 < P < PN3 (c) and PN3 < P < PP (d).

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6. Fig. 5. P-T- (a) and T-x-projections (b) of the P-T-x-phase diagram of V-O.

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7. Fig. 6. Isothermal concentration diagram of Li-V-O.

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8. Fig. 7. Fragment of isothermal concentration diagram of Li-V-O (50 at. % ≤ O ≤ 71.4 at. %).

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