Sorption of Picolinic Acid and Iron(III) by Sulfocationite Dowex 50

G. N. Altshuler; Альтшулер Г. Н.; E. V. Ostapova; Остапова Е. В.; S. Yu. Lyrschikov; Лырщиков С. Ю.; N. S. Zakharov; Захаров Н. С.; O. G. Altshuler; Альтшулер О. Г.

doi:10.31857/S0044453723100035

Sorption of Picolinic Acid and Iron(III) by Sulfocationite Dowex 50

Authors: Altshuler G.N.¹, Ostapova E.V.¹, Lyrschikov S.Y.¹, Zakharov N.S.¹, Altshuler O.G.¹^,2
Affiliations:
1. Federal Research Center of Coal and Coal-Chemistry, Siberian Branch, Russian Academy of Sciences
2. Kemerovo State University
Issue: Vol 97, No 10 (2023)
Pages: 1488-1493
Section: PHYSICAL CHEMISTRY OF DISPERSED SYSTEMS AND SURFACE PHENOMENA
Submitted: 26.02.2025
Published: 01.10.2023
URL: https://vietnamjournal.ru/0044-4537/article/view/668642
DOI: https://doi.org/10.31857/S0044453723100035
EDN: https://elibrary.ru/IHPVCS
ID: 668642

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Abstract

An experimental study of the equilibrium distribution of cations in the system of Dowex 50 sulfonic cation exchanger and an aqueous solution of picolinic acid and iron chloride was carried out. A high concentration of iron and picolinic acid complexes was obtained in the Dowex 50 sulfonic cationite phase. The possibility of calculating the equilibrium counterionic composition of Dowex 50 sulfonic cationite from the equilibrium constants of binary ion exchanges and the known composition of the solution is shown. Sulfocationite Dowex 50 is proposed as a container for biologically active preparations based on picolinic acid and Fe3+ cations.

Keywords

sulfonic cationite Dowex 50, picolinic acid, iron cations, sorption

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