Synthesis and Study of the Properties of Porous Carbon–Carbon Nanocomposites with Nitrogen-Containing Carbon Nanofibers

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Abstract

The possibility of synthesizing carbon–carbon nanocomposites with nanofibers embedded in a carbon matrix by two-stage dehydrochlorination (under the action of alkali followed by carbonization) of a carbon-chain chloropolymer has been shown. Chlorinated polyvinyl chloride was used as the initial chloropolymer, and nitrogen-containing carbon nanofibers (N-CNFs) were used as a nanoscale component. The structure of the resulting nanocomposites was examined by electron microscopy and the texture parameters were studied using low-temperature nitrogen adsorption–desorption. The introduction of N-CNFs into the carbon matrix and the activation of the resulting carbon–carbon nanocomposite in an atmosphere of CO2 contributed to the formation of a micro- and mesoporous material with a specific surface area of ~1100 m2/g. It was shown that the resulting nanocomposites were characterized by high energy capacity and energy efficiency when tested as electrodes of electrochemical supercapacitors.

About the authors

Yu. G. Kryazhev

Center of New Chemical Technologies BIC, Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences

Email: carbonfibre@yandex.ru
644040, Omsk, Russia

O. Yu. Pod”yacheva

Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences

Email: pod@catalysis.ru
630090, Novosibirsk, Russia

M. V. Trenikhin

Center of New Chemical Technologies BIC, Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences

Email: tremv@yandex.ru
644040, Omsk, Russia

T. I. Gulyaeva

Center of New Chemical Technologies BIC, Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences

Email: tangul-8790@ihcp.ru
644040, Omsk, Russia

I. V. Anikeeva

Center of New Chemical Technologies BIC, Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences

Email: irina_anikeeva@inbox.ru
644040, Omsk, Russia

Yu. M. Vol’fkovich

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: yuvolf40@mail.ru
119071, Moscow, Russia

A. Yu. Rychagov

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Author for correspondence.
Email: rychagov69@mail.ru
119071, Moscow, Russia

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Copyright (c) 2023 Ю.Г. Кряжев, О.Ю. Подъячева, М.В. Тренихин, Т.И. Гуляева, И.В. Аникеева, Ю.М. Вольфкович, А.Ю. Рычагов