Sorption properties of silicate materials from straw rice and vermiculites

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Resumo

A number of silicate and aluminosilicate sorption materials have been synthesized using rice straw as a silicon source. The dependence of sorption properties with respect to methylene blue, as well as density and moisture capacity on the composition is investigated. It is shown that the sorption capacity of silicate materials from vegetable raw materials is several times greater than that of natural aluminosilicates – vermiculite and materials based on it obtained by chemical modification. The presence of an organic component in the composition of the obtained biogenic materials contributes to a higher sorption capacity. The density and moisture capacity of the synthesized materials are determined.

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Sobre autores

A. Panasenko

Institute of Chemistry of the Far Eastern Branch of the RAS

Autor responsável pela correspondência
Email: panasenko@ich.dvo.ru
Rússia, prosp. of the 100th Anniversary of Vladivostok 159d, Vladivostok 690022

S. Terminov

Institute of Chemistry of the Far Eastern Branch of the RAS

Email: panasenko@ich.dvo.ru
Rússia, prosp. of the 100th Anniversary of Vladivostok 159d, Vladivostok 690022

N. Shapkin

Far Eastern Federal University

Email: panasenko@ich.dvo.ru
Rússia, p. Ajax 10, Russian Island, Vladivostok 690090

A. Holomeidik

Institute of Chemistry of the Far Eastern Branch of the RAS

Email: panasenko@ich.dvo.ru
Rússia, prosp. of the 100th Anniversary of Vladivostok 159d, Vladivostok 690022

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2. Fig. 1. Yield and sorption capacity for methylene blue of calcium silicate and silicon dioxide samples at different pH (a, b) and temperature (c, d) of the reaction medium

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3. Fig. 2. IR spectra and X-ray diffraction patterns of samples: a, c – from plant materials, b, d – from mineral

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4. Fig. 3. Microphotographs of samples from mineral (a, sample 2) and plant raw materials (b, sample 8)

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5. Fig. 4. Sorption capacity (MC) of biogenic sodium aluminosilicate (sample 8): (a) before treatment after calcination, (b) after treatment with DMSO

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6. Fig. 5. Sorption capacity of biogenic sodium aluminosilicate (sample 8) after 4 regeneration cycles

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