Structural-phase states and properties of medium-entropy amorphous soft magnetic ribbons of the Fe-Co-Si-B-P alloy system

Capa

Citar

Texto integral

Acesso aberto Acesso aberto
Acesso é fechado Acesso está concedido
Acesso é fechado Acesso é pago ou somente para assinantes

Resumo

An analysis of the structural-phase states, mechanical, and magnetic properties of amorphous alloys (Fe,Co)82B13Si5 and (Fe,Co)82B12Si4P2, produced by melt spinning, has been conducted. The distribution of elemental composition was traced, revealing phase separation in silicon and cobalt. It was demonstrated that the experimentally determined saturation induction values (1.7–1.8 T) and coercivity (18–20 A/m) exhibit virtually no dependence on variations in ribbon composition within the studied elemental range. The ultimate tensile strength (~162 MPa) and elongation at break (~0.23%) indicate low ductility in the examined ribbons. However, the elastic modulus was notably high, reaching 81.5 MPa.

Sobre autores

V. Gromov

Siberian State Industrial University

Autor responsável pela correspondência
Email: gromov@physics.sibsiu.ru
Novokuznetsk

A. Semin

Siberian State Industrial University

Email: gromov@physics.sibsiu.ru
Novokuznetsk

Yu. Ivanov

Institute of High Current Electronics, Siberian Branch of the Russian Academy of Sciences

Email: yufi55@mail.ru
Tomsk

S. Panin

Institute of Strength Physics and Materials Science

Email: paninsergey71@mail.ru
Tomsk

P. Mogilnikov

I.P. Bardin Central Research Institute for Ferrous Metallurgy

Email: pavel_mog@mail.ru
Moscow

I. Litovchenko

Institute of Strength Physics and Materials Science

Email: gromov@physics.sibsiu.ru
Tomsk

I. Selivanov

Siberian State Industrial University

Email: gromov@physics.sibsiu.ru
Novokuznetsk

Bibliografia

  1. Yeh, J.W. Nanostructured high-entropy alloys with multiple principal elements: Novel alloy design concepts and outcomes / Yeh J.W., Chen S.K, Lin S.J., Gan J.Y., Chin T.S., Shun T.T., Tsau C.H., Chang S.Y. // Adv. Eng. Mater. 2004. V.6. P.299-303.
  2. Cantor, B. Microstructural development in equiatomic multicomponent alloys / B. Cantor, I.T.H. Chang, P. Knight, A.J.B. Vincent // Mater. Sci. Eng. A. 2004. V.375. P.213-218.
  3. Ye, Y.F. High-entropy alloy: Challenges and prospects / Ye, Y.F., Wang Q., Lu J., Liu C.T., Yang, Y. // Mater. Today 2016. V.19. P.349-362.
  4. Miracle, D.B. A critical review of high entropy alloys and related concepts / D.B. Miracle, O.N. Senkov // Acta Materialia. 2017. V.122. P.448-511.
  5. Li, Y.H. New soft magnetic Fe25Co25Ni25(P,C,B)25 high entropy bulk metallic glasses with large supercooled liquid region / Li Y.H., Zhang W., Qi T.L. // J. Alloy. Compd. 2017. V.693. P.25-31.
  6. Wang, C. Effect of P on glass forming ability, magnetic properties and oxidation behavior of FeSiBP amorphous alloys / Wang C., He A., Wang A., Pang J., Liang X., Li Q., Chang C., Qiu K., Wang X. // Intermetallics 2017. V.84. P.142-147.
  7. Li, P. A ductile high entropy alloy with attractive magnetic properties / Li P., Wang A., Liu C.T. // J. Alloy. Compd. 2017. V.694. P.55-60.
  8. Zhang, Y. High-entropy alloys with high saturation magnetization, electrical resistivity, and malleability / Zhang Y., Zuo T., Cheng Y., Liaw P.K. // Sci. Rep. 2013. V.3. Art.1455.
  9. Hinte, C. Pattern-forming nanoprecipites in NiTi-related high-entropy shape memory alloys / C. Hinte, K. Bariente, J. Streinbrücker, G. Gerstein, M.A. Swider, S. Herbst [et al.] // Scripta Materialia. 2020. V.86. P.132-135.
  10. Рогачев, А.С. Структура, стабильность и свойства высокоэнтропийных сплавов / А.С. Рогачев // ФММ. 2020. Т.121. No8. С.807-841. - (Rogachev, A.S. Structure, stability and properties of high-entropy alloys / A.S. Rogachev // Physics of Metals and Metallography. 2020. V.121(8). P.807-841.)
  11. Karimi, M.A. Fabrication of a novel magnetic high entropy alloy with desirable mechanical properties by mechanical alloying and spark plasma sintering / M.A. Karimi, M. Shamanian, M.H. Enayati, M. Adamzadeh, M. Imani // J. Manul. Process. 2022. V.84. P.859-870.
  12. Li, C. New ferromagnetic (Fe1/3Co1/3Ni1/3)80(P1/2B1/2)20 high entropy bulk metallic glass with superior magnetic and mechanical properties / C. Li, Q. Li, M. Li, C. Chang, H. Li, Y. Dong, Y. Sun // J. Alloy. Compd. 2019. V.791. P.947-951.
  13. Vaidya, M. Amorphization in equiatomic high entropy alloys / M. Vaidya, S. Armugam, S. Kashyap, B.S. Murty // J. Non-Cryst. Solids. 2015. V.413. P.8-14.
  14. Shu, F.Y. Structure and high-temperature property of amorphous composite coating synthesized by laser cladding FeCrCoNiSiB high-entropy alloy powder / Shu F.Y., Liu S., Zhao H.Y., He W.X., Sui S.H., Zhang J., He P., Xu B.S. // J. Alloy. Compd. 2017. V.731. P.662-666.
  15. Кекало, И.Б. Процессы структурной релаксации и физические свойства аморфных сплавов / И.Б. Кекало; монография в 2 т. Т.2. - М.: Издат. Дом МИСиС, 2016. 650 с. - (Kekalo, I.B. Structural relaxation processes and physical properties of amorphous alloys / I.B. Kekalo; Monograph. in 2 v. V.2. - Moscow: MISIS Publishing House, 2016. 650 p.)
  16. Семин, А.П. Структура и свойства ленты магнитомягкого сплава Fe-Co-Ni-Si-B, изготовленной методом спиннингования / А.П. Семин, В.Е. Громов, Ю.Ф. Иванов, С.В. Панин, Е.А. Колубаев, И.Ю. Литовченко, С.В. Боровский // Физическая мезомеханика. 2024. Т.27. No5. С.63-70. - (Semin, A.P. Structure and properties of Fe-Co-Ni-Si-B soft magnetic alloy ribbons produced by melt spinning / A.P. Semin, V.E. Gromov, Yu.F. Ivanov, S.V. Panin, E.A. Kolubaev, I.Yu. Litovchenko, S.V. Borovsky // Physical Mesomechanics. 2024. V.27(5). P.63-70.)
  17. Gromov, V.E. Structure and properties of a ribbon from FeCoNiSiB high-entropy alloy / V.E. Gromov, A.I. Potekaev, A.P. Semin, E.A. Kolubaev, P.S. Mogilnikov, Yu.F. Ivanov, S.V. Panin, S.V. Borovsky, I.Yu. Litovchenko, B.A. Kornienkov // Russian Physics J. 2024. V.67. No6. P.756-764.
  18. Han, Y. New Fe-based soft magnetic amorphous alloys with high saturation magnetization and good corrosion resistance for dust core application / Han Y., Kong F.L., Han F.F., Inoue A., Zhu S.L., Shalaan E., Al-Marzouki F. // Intermetallics. 2016. V.76. P.18-25. doi: 10.1016/j.intermet.2016.05.011.
  19. Roy, R.K. Compositional optimization of high induction (>1,7 T) FeCo-based nanocomposite alloys with enhancement of thermo-physical and magnetic properties / R.K. Roy, P. Murugaiyan, A.K. Panda, A. Mitra // Physica. B: Condensed Mater. 2019. V.566. P.71-76. doi: 10.1016/j.physb.2019.04.034.
  20. Hou, L. Thermal and magnetic properties of Fe(Co)BCCu amorphous alloys with high saturation magnetization of 1.77 T / Hou L., Li M., Jiang C., Fan X., Luo Q., Chen S., Li W. // J. Alloys Comp. 2021. V.853. Art.157071. doi: 10.1016/j.jallcom.2020.157071.
  21. Wang, F. Excellent soft magnetic Fe-Co-B-based amorphous alloys with extremely high saturation magnetization above 1,85 T and low coercivity below 3 A/m / F. Wang, A. Inoue, Y. Han // J. Alloys Comp. 2017. V.711. P.132-142.
  22. Wang, C. Effect of P on glass forming ability, magnetic properties and oxidation behavior of FeSiBP amorphous alloys / Wang C., He A., Wang A., Pang J., Liang X., Li Q., Wang X. // Intermetallics. 2017. V.84. P.142-147. doi: 10.1016/j.intermet.2016.12.024.
  23. Hou, L. High Bs of FePBCCu nanocrystalline alloys with excellent soft-magnetic properties / Hou L., Yang W., Luo Q., Fan X., Liu H., Shen B. // J. Non-Crystalline Solids. 2020. V.530. Art.119800. doi: 10.1016/j.jnoncrysol.2019.119800.
  24. Пат. РФ No RU2262540. Способ производства изотропной электротехнической стали с фосфором / Кондратков Д.А.; заявл. 12.10.2004; опубл. 20.10.2005. - (Pat. No. RU2262540. Method for producing isotropic electrical steel with phosphorus / Kondratkov D.A.; application date 12.10.2004; publication date 20.10.2005.)
  25. Чеглов, А.Е. Влияние фосфора на структуру нелегированной изотропной электротехнической стали / А.Е. Чеглов, Д.А. Кондратков, А.Б. Полушкин, А.А. Заверюха // Сталь. 2005. No9. С.67-69. - (Cheglov, A.E. Effect of phosphorus on the structure of unalloyed isotropic electrical steel / A.E. Cheglov, D.A. Kondratkov, A.B. Polushkin, A.A. Zaverukha // Steel. 2005. No9. P.67-69.)

Arquivos suplementares

Arquivos suplementares
Ação
1. JATS XML

Declaração de direitos autorais © Russian Academy of Sciences, 2025