The first example of synthesis of a new class of spiroboracarbocycles via cycloboration of methylenecycloalkanes with PhBCl2 catalyzed by Cp2TiCl2

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详细

Cp2TiCl2-catalyzed cycloboration of methylenecycloalkanes with PhBCl2 in the presence of metallic Mg to obtain a novel spiroboracarbocycles in good yields (70-80%) is reported for the first time. The structure and properties of spiro-fused boriranes were studied using 11B, 1H, 13C NMR spectroscopy and DOSY experiments. 1-Phenyl-substituted boraspiranes are stable in solution at room temperature for a day.

作者简介

L. Tulyabaeva

Institute of Petrochemistry and Catalysis, Ufa Federal Research Centre, Russian Academy of Sciences

Email: khusainova_ink@mail.ru

R. Salakhutdinov

Institute of Petrochemistry and Catalysis, Ufa Federal Research Centre, Russian Academy of Sciences

Email: khusainova_ink@mail.ru

T. Tyumkina

Institute of Petrochemistry and Catalysis, Ufa Federal Research Centre, Russian Academy of Sciences

Email: khusainova_ink@mail.ru

A. Tulyabaev

Institute of Petrochemistry and Catalysis, Ufa Federal Research Centre, Russian Academy of Sciences

Email: khusainova_ink@mail.ru

U. Dzhemilev

Institute of Petrochemistry and Catalysis, Ufa Federal Research Centre, Russian Academy of Sciences

Email: khusainova_ink@mail.ru

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