Synthesis of hexa-substituted benzene derivative based on 4-pyridinecarboxaldehyde and malononitrile

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Resumo

The present work reports the synthesis of a new compound 2-amino-4,6-di(pyridin-4-yl)benzene-1.3.5-tricarbonitrile as a result of the reaction of two moles of 2-(pyridin-4-ylmethylene)malononitrile with one mole of malononitrile in the presence of methylpiperazine as a catalyst. The structure of the obtained product was confirmed by NMR and X-ray. A plausible reaction mechanism is presented.

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Sobre autores

I. Mamedov

Baku State University

Autor responsável pela correspondência
Email: bsu.nmrlab@gmail.com
ORCID ID: 0000-0002-5757-9899

химический факультет

Azerbaijão, ul. Z. Khalilova, 23, Baku, Az-1148

F. Naghiyev

Baku State University

Email: bsu.nmrlab@gmail.com
ORCID ID: 0009-0003-9325-1756

химический факультет

Azerbaijão, ul. Z. Khalilova, 23, Baku, Az-1148

I. Yakushev

Kurnakov Institute of General and Inorganic Chemistry of RAS

Email: bsu.nmrlab@gmail.com
Rússia, Leninsky prosp., 31, Moscow, 119071

V. Khrustalev

Peoples’ Friendship University of Russia (RUDN University); dZelinsky Institute of Organic Chemistry RAS

Email: bsu.nmrlab@gmail.com
ORCID ID: 0000-0001-8806-2975
Rússia, ul. Miklukho-Maklaya, 6, Moscow, 117198; Leninsky prosp., 47, Moscow, 119991

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