Study of reaction of (E)-(3-aryl-3-oxoprop-1-en-1-yl)triphenylphosphonium bromides with 2-aminopyridine
- Autores: Khachikyan R.J.1, Harutyunyan K.K.1, Ayvazyan A.G.1, Hovakimyan Z.G.1
 - 
							Afiliações: 
							
- Institute of Organic Chemistry, Scientific and Technological Center of Organic and Pharmaceutical Chemistry, National Academy of Sciences of Armenia
 
 - Edição: Volume 61, Nº 2 (2025)
 - Páginas: 197-202
 - Seção: Articles
 - URL: https://vietnamjournal.ru/0514-7492/article/view/684333
 - DOI: https://doi.org/10.31857/S0514749225020109
 - EDN: https://elibrary.ru/DHFDTU
 - ID: 684333
 
Citar
Texto integral
Resumo
(E)-(3-Aryl-3-oxoprop-1-en-1-yl)triphenylphosphoniumbromides react with 2-aminopyridine to form [(2-aryl-3-imidazo-[1,2-α-]pyridin-3-yl)methyl]triphenylphosphoniumbromides. An alternative scheme of the reactions is proposed, including an initial attack of the nucleophile on the carbonyl group.
Texto integral
Sobre autores
R. Khachikyan
Institute of Organic Chemistry, Scientific and Technological Center of Organic and Pharmaceutical Chemistry, National Academy of Sciences of Armenia
							Autor responsável pela correspondência
							Email: khachikyanraya@gmail.com
				                	ORCID ID: 0009-0006-2014-7861
				                																			                												                	Armênia, 							prosp. Azatutyan, 26, Yerevan, 0014						
K. Harutyunyan
Institute of Organic Chemistry, Scientific and Technological Center of Organic and Pharmaceutical Chemistry, National Academy of Sciences of Armenia
														Email: khachikyanraya@gmail.com
				                	ORCID ID: 0000-0002-3274-1239
				                																			                												                	Armênia, 							prosp. Azatutyan, 26, Yerevan, 0014						
A. Ayvazyan
Institute of Organic Chemistry, Scientific and Technological Center of Organic and Pharmaceutical Chemistry, National Academy of Sciences of Armenia
														Email: khachikyanraya@gmail.com
				                	ORCID ID: 0000-0002-3224-0549
				                																			                												                	Armênia, 							prosp. Azatutyan, 26, Yerevan, 0014						
Z. Hovakimyan
Institute of Organic Chemistry, Scientific and Technological Center of Organic and Pharmaceutical Chemistry, National Academy of Sciences of Armenia
														Email: khachikyanraya@gmail.com
				                	ORCID ID: 0009-0000-1604-5834
				                																			                												                	Rússia, 							prosp. Azatutyan, 26, Yerevan, 0014						
Bibliografia
- Хачикян Р.Дж., Овакимян З.Г., Паносян Г.А., Тамазян Р.А., Айвазян А.Г. ЖОХ, 2017, 87, 1110–1116. doi: 10.1134/S1070363217070 106
 - Хачикян Р.Дж., Овакимян З.Г., Карамян Э.О., Паносян Г.А. ЖОХ, 2019, 89, 218–222. doi: 10.1134/S1070363219020087
 - Zbiral E. Tetrahedron Lett., 1970, 58, 5107–5110. doi: 10.1016/S0040-4039(00)96998-3
 - Roth M., Dubs P., Gotschi E., Eschenmoser A. Helv. Chim. Acta., 1971, 54, 710–734. doi: 10.1002/hlca.19710540229
 - Хачикян Р.Дж., Овакимян З.Г., Карамян Э.О., Балян А.А., Паносян Г.А. Хим. ж. Армении, 2021, 74, 154–160.
 - Zbiral E., Bauer E. Tetrahedron, 1972, 28, 4189–4196. doi: 10.1016/S0040-4020(01)93649-x
 - Zbiral E., Drescher M. Syntesis, 1988, 9, 735–739. doi: 10.1055/S-1988-27693
 - Мегера И.В., Лебедев Л.Б., Шевчук М.И. ЖОХ, 1981, 51, 54–57.
 - Townsend L.B. and. Shram K.H. Tetrahedron Lett., 1974, 1345–1348. doi: 10.1016/S0040-4039(01)82484-9
 - Hugl E., Schulz G. and Zbiral E. Liebigs Ann. Chem, 1973, 278–289. doi: 10.1002/jlac.197319730216
 - Хачикян Р.Дж., Овакимян З.Г., Паносян Г.А., Тамазян Р.А., Айвазян А.Г. ЖОХ, 2014, 84, 453–456. doi: 10.1134/S1070363214030177
 - North A.C.T., Phillips D.C., Mathews F.S. Acta Crystallogr. (A), 1968, 24, 351–359. doi: 10.1107/S0567739468000707
 - Sheldrick G.M. Acta Crystallogr., 2015, 71, 3–8. doi: 10.1107/S2053229614024218
 
Arquivos suplementares
				
			
						
						
					
						
						
									





