SAXS Application for the Determination of the Gold Nanoparticle Sizes in Au/C Catalysts: Advantages over Other Methods

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In the case of Au/C catalysts have been shown advantages of application SAXS with masking liquid technique for determining supported metal particle sizes compared with TEM and XRD as standard methods. According to SAXS data particle size distributions of gold in a wide range (1–50 nm) were obtained with full consideration of all size fractions of particles present in the samples under study. Also values of the mass fraction of “X-ray amorphous” gold particles with size less than 4 nm (WSAXS) were determined. It has been found that the oxidative treatment of the carbon support before deposition of metallic gold precursor complexes has a significant effect on the size distribution of gold particles in the final catalyst. Comparison of the results of measuring the rate of CO oxidation by an excess of moist air at 40°C on Au/C catalysts with the (WSAXS) values found for these catalysts showed that the catalytic activity increases exponentially as (WSAXS) increases. High activity in CO oxidation reaction was demonstrated by Au/C catalysts with (WSAXS) ≥ 80%.

作者简介

Yu. Larichev

Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University

编辑信件的主要联系方式.
Email: ylarichev@gmail.com
Russia, 630090, Novosibirsk, рrosp. Akad. Lavrentieva 5; Russia, 630090, Novosibirsk, Pirogov st., 1

B. Moroz

Novosibirsk State University

Email: ylarichev@gmail.com
Russia, 630090, Novosibirsk, Pirogov st., 1

P. Pyrjaev

Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences

Email: ylarichev@gmail.com
Russia, 630090, Novosibirsk, рrosp. Akad. Lavrentieva 5

V. Bukhtiyarov

Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University

Email: ylarichev@gmail.com
Russia, 630090, Novosibirsk, рrosp. Akad. Lavrentieva 5; Russia, 630090, Novosibirsk, Pirogov st., 1

参考

  1. Haruta M. // Catal. Today. 1997. V. 36. P. 153.
  2. Bond G.C., Louis C., Thompson D.T. Catalysis by Gold. London: Imperial College Press, 2006. 366 p.
  3. Кустов Л.М. // Изв. АН. Сер. хим. 2013. № 4. С. 870.
  4. Heterogeneous Gold Catalysts and Catalysis. Ed. Z. Ma, S. Dai. Cambridge (UK): Royal Society of Chemistry, 2014.
  5. Haruta M., Tsubota S., Kobayashi T., Kageyama H., Genet M.J., Delmon B. // J. Catal. 1993. V. 144. P. 175.
  6. Zanella R., Giorgio S., Shin C.-H., Henry C.R., Louis C. // J. Catal. 2004. V. 222. P. 357.
  7. Chen M.S., Goodman D.W. // Catal. Today. 2006. V. 111. P. 22.
  8. Kung M.C., Davis R.J., Kung H.H. // J. Phys. Chem. C. 2007. V. 111. P. 11767.
  9. Hvolbaek B., Janassens T.V.W., Clausen B.S., Falsig H., Christensen C.H., Norskov J.K. // Nanotoday. 2007. V. 2. P. 14.
  10. Mohr C., Hofmeister H., Claus P. // J. Catal. 2003. V. 213. P. 86.
  11. Hartfelder U., Kartusch C., Makosch M., Rovezzi M., Sa J., van Bokhoven J.A. // Catal. Sci. Technol. 2013. V. 3. P. 454.
  12. Смирнов В.В., Николаев С.А., Муравьева Г.П., Тюрина Л.А., Васильков А.Ю. // Кинетика и катализ. 2007. Т. 48. С. 1.
  13. Della Pina C., Falletta E., Rossi M., Sacco A. // J. Catal. 2009. V. 263. P. 92.
  14. Delidovich I.V., Moroz B.L., Taran O.P., Gromov N.V., Pyrjaev P.A., Prosvirin I.P., Bukhtiyarov V.I., Parmon V.N. // Chem. Eng. J. 2013. V. 223. P. 921.
  15. Bianchi C., Porta F., Prati L., Rossi M. // Top. Catal. 2000. V. 13. P. 231.
  16. Li R., Yan X., Zhu X., Shou D., Zhou X., Dai Y., Yang Y. // Catal. Today. 2017. V. 298. P. 269.
  17. Qi C., Akita T., Okumura M., Haruta M. // Appl. Catal. A: Gen. 2004. V. 263. P. 19.
  18. Dimitratos N., Lopes-Sancez J.A., Lennon D., Porta F., Prati L., Villa A. // Catal. Lett. 2006. V. 108. P. 147.
  19. Ona J.P., Latonen R.-M., Kumar N., Peurla M., Angervo I., Grenman H. // Electrochim. Acta. 2022. V. 426. № 140754.
  20. Bond G.C. // Molecules. 2012. V. 17. P. 1716.
  21. Moroz B.L., Pyrjaev P.A., Zaikovskii V.I., Bukhtiyarov V.I. // Catal. Today. 2009. V. 144. P. 292.
  22. Riello P., Canton P., Benedetti A. // Langmuir. 1998. V. 14. P. 6617.
  23. Пыряев П.А., Мороз Б.Л., Зюзин Д.А., Герасимов Е.А., Нартова А.В., Бухтияров В.И. // Кинетика и катализ. 2010. Т. 51. С. 914.
  24. Bulushev D.A., Kiwi Minsker L., Yuranov I., Suvorova E.I., Buffat P.A., Renken A. // J. Catal. 2002. V. 210. P. 149.
  25. Della Pina C., Falletta E., Rossi M. // Chem. Soc. Rev. 2012. V. 41. P. 350.
  26. Villa A., Dimitratos N., Chan-Thaw C.E., Hammond C., Prati L., Hutchings G.H. // Acc. Chem. Res. 2015. V. 48. P. 1403.
  27. Donoeva B., Masoud N., de Jongh P.E. // ACS Catal. 2017. V. 7. P. 4581.
  28. Pyrjaev P.A., Yuschenko D.Y., Moroz B.L., Pai Z.P., Bukhtiyarov V.I. // ChemistrySelect. 2019. V. 4. P. 10576.
  29. Ruvinsky P.S., Pronkin S.N., Zaikovskii V.I., Bernhardt P., Savinova E.R. // Phys. Chem. Chem. Phys. 2008. V. 10. P. 6665.
  30. Simonov A.N., Pyrjaev P.A., Moroz B.L., Bukhtiyarov V.I., Parmon V.N. // Electrocatalysis. 2012. V. 3. P. 119.
  31. Prati L., Martra G. // Gold Bull. 1999. V. 32. P. 96.
  32. Feigin L.A., Svergun D.I. Structure Analysis by Small-Angle X-Ray and Neutron Scattering. New York: Plenum Press, 1987.
  33. Sharma P., Darabdhara G., Reddy T.M., Borah A., Bezboruah P., Gogoi P., Hussain N., Sengupta P., Das M.R. // Catal. Commun. 2013. V. 40. P. 139.
  34. Padayachee D., Golovko V., Ingham B., Marshall A.T. // Electrochim. Acta. 2014. V. 120. P. 398.
  35. Simenyuk G.Yu., Zakharov Yu.A., Pavelko N.V., Dodonov V.G., Pugachev V.M., Puzynin A.V., Manina T.S., Barnakov Ch.N., Ismagilov Z.R. // Catal. Today. 2015. V. 249. P. 220.
  36. Benedetti A., Polizzi S., Riello P., Pinna F., Goerigk G. // J. Catal. 1998. V. 171. P. 345.
  37. Benedetti A., Bertoldo L., Canton P., Goerigk G., Pinna F., Riello P., Polizzi S. // Catal. Today. 1999. V. 49. P. 485.
  38. Gann E.L. // J. Phys. Chem. 1958. V. 62. P. 928.
  39. Whyte T.E., Kirklin P.W., Gould R.W., Heinemann H. // J. Catal. 1972. V. 25. P. 407.
  40. Larichev Yu.V., Tuzikov F.V. // J. Appl. Crystallogr. 2013. V. 46. P. 752.
  41. Salnikova K.E., Matveeva V.G., Larichev Yu.V., Bykov A.V., Demidenko G.N., Shkileva I.P., Sulman M.G. // Catal. Today. 2019. V. 329. P. 142.
  42. Salnikova K.E., Larichev Yu.V., Sulman E.M., Bykov A.V., Sidorov A.I., Demidenko G.N., Sulman M.G., Bronstein L.M., Matveeva V.G. // ChemPlusChem. 2020. V. 85. P. 1697.
  43. Taratayko A., Larichev Yu., Zaikovskii V., Mikheeva N., Mamontov G. // Catal. Today. 2021. V. 375. P. 576.
  44. Mason W.R., Grey H.B. // J. Am. Chem. Soc. 1968. V. 90. P. 5721.
  45. Skibsted L.H., Bjerrum J. // Acta Chem. Scand. 1974. V. A28. P. 740.
  46. Plaksin G.V., Baklanova O.N., Lavrenov A.V., Likholobov V.A. // Solid Fuel Chem. 2014. V. 48. P. 349.
  47. Симонов П.А. Катализаторы Pd/C: изучение физико-химических процессов формирования активного компонента из H2PdCl4. Дисс. … канд. хим. наук. Новосибирск: Ин-т катализа СО РАН. 2000. 159 с.
  48. Aguilar C., Garcia R., Soto-Garrido G., Arriagada R. // Appl. Catal. B: Environ. 2003. V. 46. P. 229.
  49. Karnaukhov A.P., Fenelonov V.B., Gavrilov V.Yu. // Pure Appl. Chem. 1989. V. 61. P. 1913.
  50. Konarev P.V., Petoukhov M.V., Volkov V.V., Svergun D.I. // J. Appl. Crystallogr. 2006. V. 39. P. 277.
  51. Полуянов С.А., Тузиков Ф.В., Ларичев Ю.В., Цыбуля С.В. // Журн. структ. хим. 2016. Т. 57. С. 809.
  52. Simonov A.N., Pyrjaev P.A., Simonov P.A., Moroz B.L., Cherepanova S.V., Zyuzin D.A., Bukhtiyarov V.I., Parmon V.N. // J. Mol. Catal. A: Chem. 2012. V. 353–354. P. 204.
  53. Simonov P.A., Romanenko A.V., Prosvirin I.P., Kryukova G.N., Chuvilin A.L., Bogdanov S.V., Moroz E.M., Likholobov V.A. // Stud. Surf. Sci. Catal. 1998. V. 118. P. 15.
  54. Bulushev D.A., Yuranov I., Suvorova E.I., Buffat P.A., Kiwi Minsker L. // J. Cat. 2004. V. 224. P. 8.
  55. Андерсон Дж. Структура металлических катализаторов. М.: Мир, 1978. 482 с.
  56. Бухтияров В.И., Мороз Б.Л., Бекк И.Э., Просвирин И.П. // Катализ в промышленности. 2008. Спецвыпуск: Нанотехнологии в катализе − перспектива прорывных инноваций XXI века. С. 44.
  57. Auer P.A., Freund A., Pietsch J., Tacke T. // Appl. Catal. A: Gen. 1998. V. 173. P. 259.
  58. Тарасенко Ю.А., Болдырева Н.А., Герасимюк И.П., Лапко В.Ф., Яцимирский В.К. // Катализ и нефтехимия. 2003. № 11. С. 51.

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