Copper(II) o-Iminophenolate Complexes Based on Catecholaldimines

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Resumo

The exchange reactions of 4,6-di-tert-butylpyrocatechols containing in position 3 different N‑aryliminomethyl groups (aryl is p-halophenyl; halogen is fluorine (I), chlorine (II), bromine (III), and iodine (IV); p-tolyl (V)) with copper(II) acetate in a molar ratio of 2 : 1 afford planar square copper(II) o‑iminophenolate complexes of the general formula [(R-CatH)2Cu], where R is the aryl substituent in the Ar–N=CH group. The molecular structures of complexes I, III, and V in the crystalline state are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 2227448 (I), 2226727 (III), and 2227449 (V)). The electrochemical properties of compounds I–V are studied by cyclic voltammetry.

Sobre autores

S. Baryshnikova

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

Email: baryshnikova@iomc.ras.ru
Россия, Нижний Новгород

M. Arsen’ev

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

Email: baryshnikova@iomc.ras.ru
Россия, Нижний Новгород

R. Rumyantsev

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

Email: baryshnikova@iomc.ras.ru
Россия, Нижний Новгород

I. Yakushev

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

Email: ilya.yakushev@igic.ras.ru
Россия, 119991, Москва, Ленинский пр-т, 31

A. Poddel’skii

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

Autor responsável pela correspondência
Email: baryshnikova@iomc.ras.ru
Россия, Нижний Новгород

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Declaração de direitos autorais © С.В. Барышникова, М.В. Арсеньев, Р.В. Румянцев, И.А. Якушев, А.И. Поддельский, 2023