Controlling the Degree of Substitution of Lanthanides in Anionic Positions in Complexes [CeNi6(Ala)12][(LnxCe1 – x)(NO3)3(OH)3(H2O)]

D. D. Semeshkina; Семешкина Д. Д.; Yu. A. Belousov; Белоусов Ю. А.; A. R. Savarets; Саварец А. Р.; M. V. Berekchiyan; Берекчиян М. В.; V. D. Dolzhenko; Долженко В. Д.

doi:10.31857/S0044457X23601141

Controlling the Degree of Substitution of Lanthanides in Anionic Positions in Complexes [CeNi6(Ala)12][(LnxCe1 – x)(NO3)3(OH)3(H2O)]

Authors: Semeshkina D.D.¹, Belousov Y.A.¹^,2, Savarets A.R.¹^,3, Berekchiyan M.V.¹, Dolzhenko V.D.¹^,3
Affiliations:
1. Moscow State University
2. Lebedev Physical Institute, Russian Academy of Sciences
3. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Issue: Vol 68, No 9 (2023)
Pages: 1303-1311
Section: КООРДИНАЦИОННЫЕ СОЕДИНЕНИЯ
URL: https://vietnamjournal.ru/0044-457X/article/view/666278
DOI: https://doi.org/10.31857/S0044457X23601141
EDN: https://elibrary.ru/WNIPAX
ID: 666278

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Abstract

A series of 32 heterometallic ionic complexes [CeNi6(Ala)12][(LnxCe1 – x)(NO3)3(OH)3(H2O)] (Ln = Tb, Ho, Er, Tm, Yb, Lu) have been synthesized and characterized by XRD and IPC-MS. The dependence of the degree of substitution of lanthanides in the anionic position on the nature of Ln3+ and precipitation conditions has been determined. The processes occurring during the formation of the complexes have been studied by UV-Vis, diffuse reflectance electronic spectroscopy, and ICP-MS. Based on these data, a model of equilibria in the system was proposed to explain the increase in the degree of substitution of Ln in the anionic position in the lanthanide series and with a decrease in the concentration of Ce and Ln in the solution from which precipitation is performed.

Keywords

3d–4f heterometallic complexes, lanthanides, nickel, amino acids, alanine degree of substitution

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