Modeling of the processing of alkanthiols into disulfides using ionic liquids

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A functional model of environmentally safe and energy-saving technology for removal of toxic alcanthiols for their processing into practically useful disulfides using ionic liquids is proposed. The process is based on mediator electrooxidation of alcanthiols removed from liquid fuels by extraction with ionic liquids. The developed method of indirect electrosynthesis of symmetrical disulfides is realized under mild conditions, in the environment of electrically conductive ionic liquids, acting as a solvent and background electrolyte. The use of mediator contributes to the increase of electrosynthesis efficiency and reduction of energy consumption for its realization in comparison with the direct electrochemical oxidative transformation of alcanthiols into disulfides.

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E. Shinkar

Astrakhan State Technical University

编辑信件的主要联系方式.
Email: elenshin@rambler.ru
俄罗斯联邦, Astrakhan

A. Tishkov

Astrakhan State Technical University

Email: elenshin@rambler.ru
俄罗斯联邦, Astrakhan

A. Okhlobystin

Gazprom Pererabotka LLC

Email: elenshin@rambler.ru
俄罗斯联邦, Novy Urengoy

N. Berberova

Astrakhan State Technical University

Email: elenshin@rambler.ru
俄罗斯联邦, Astrakhan

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2. Fig. 1. Schematic diagram of a diaphragm-free cell for the electrosynthesis of R2S2 based on RSH.

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3. Fig. 2. Ionic liquids studied in the work: [1-Bu-3-MeIm]BF4 (I), [1-n-Bu-4-MePy]BF4 (II), [1-Bu-3-MeIm]SO4CH3 (III), [1-Me-3-C8Im]BF4 (IV).

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4. Fig. 3. CVA of oxidation of a mixture of nBu4NBr and nHхSH (СH3СN, Pt anode (S = 2 mm2), Аg/АgСl, v = 0.1 V s–1, С(nBu4NClO4) = 0.1 M, С(nHxSH) = 0.005 M, С(nBu4NBr) = 0.004 M)

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5. Fig. 4. CVA of oxidation of nBuSH electrolysis products (C = 0.005 M) in the presence of Med in a mixture of CH3CN/IL I at a volume ratio of 3 : 1 (Pt anode (S = 2 mm2), Ag/AgCl, v = 0.1 V s–1, C(nBu4NBr) = 0.004 M, Eel = 1.0 V, τ = 90 min).

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6. Fig. 5. Diagram of the dependence of the degree of mediator regeneration (φ) on the nature of IL I–IV and the structure of RSH.

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7. Fig. 6. Functional model of the process of utilization of alkanethiols from gas condensate and their processing into disulfides.

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8. (1)

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9. (2)

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